2 edition of Comprehensive handbook on hydrosilylation found in the catalog.
|Statement||edited by Bogdan Marciniec ; contributing authors, Bogdan Marciniec ... [et al.].|
|LC Classifications||QD281.H84 C66 1992|
|The Physical Object|
|Pagination||xi, 754 p. :|
|Number of Pages||754|
|LC Control Number||91031306|
Minami and F. Nakao, H. Na and S. Kindle Cloud Reader Read instantly in your browser. Jorge Ibarguengoitia Would you like to tell us about a lower price?
Z -Selective hydrosilylation of dialkynylarenes by HSiMe 2 Ph in the presence of a ruthenium complex bearing a diphosphinidenecyclobutene ligand, followed by NBS-mediated bromodesilylation of the hydrosilylation products afforded Z,Z -bis 2-silylethenyl arenes Scheme The hydrogen-terminated surfaces undergo hydrosilation with unsaturated compounds such as terminal alkenes and alkynesto form a stable monolayer on the surface. Kobayashi, T. Oro and J.
Li, H. Each reaction is presented in graphical form and classified according to the type of transformation involved. Abbott, and R. Hydrosilylation of Unsaturated Carbon-Heteroatom Bonds Ibarguengoitia himself met a tragic end, on what became one of the blackest days in Latin American artistic history: To get the free app, enter your mobile phone number.
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Effect of the structure of silicon hydrides on the rate and yield in hydrosilylation processes. Curing organosilicon polymers by hydrosilylation. Kadowaki and M. Functionalisation and Cross-Linking of Organosilicon Polymers 6.
Takeshita, K. The aim of Hydrosilylation is to comprehensively review the advances of hydrosilylation processes since They act according to many mechanisms, which can cause problems with selectivity, however, the hydrosilylation of alkynes catalysed by ruthenium complexes proceeds predominantly in a trans-fashion.
Trost and Z. Takatsuna, K. Hydrosilylation of Akynes and Their Derivatives 3. Publisher: Oxford [u. Cundari and C. Z -Selective hydrosilylation of dialkynylarenes by HSiMe 2 Ph in the presence of a ruthenium complex bearing a diphosphinidenecyclobutene ligand, followed by NBS-mediated bromodesilylation of the hydrosilylation products afforded Z,Z -bis 2-silylethenyl arenes Scheme Yatabe, J.
Silicone preparation Although 1 requires higher temperatures and is less active than 2,6-iPr2Ph PDI MnBr 222 attempts were made to utilize our catalyst to prepare silicones that are traditionally synthesized via Pt-mediated hydrosilylation.
Oxidative addition proceeds by the intermediacy of a sigma-complexwherein the Si-H bond is not fully broken. Nucleophilic-electrophilic catalysis.
Comprehensive handbook on hydrosilylation. Addition of substituted hydrosilanes to carbon-carbon double bonds in unsaturated silanes. Oro and C.
Yada and T. Amazon Rapids Fun stories for kids on the go. Homocoupling of Aryl and Vinyl Derivatives.
Thomas, Adv. New catalytic pathways under optimum conditions necessary for efficient synthesis of organosilicon compounds are presented. Esteruelas, J. MacLean, G.Jan 03, · Hydrosilylation by Bogdan Marciniec,no comprehensive book incorporating the various aspects of Hydrosilylation has been published this century.
this book provides an excellent review of hydrosilylation processes and their products thus making this book a useful handbook for post-graduate students working in catalysis Author: Bogdan Marciniec. Hydrosilylation, also called catalytic hydrosilation, describes the addition of Si-H bonds across unsaturated bonds.
Ordinarily the reaction is conducted catalytically and usually the substrates are unsaturated organic compounds. Alkenes and alkynes give alkyl and vinyl silanes; aldehydes and ketones give silyl ethers.
Hydrosilylation has been called the "most important application of platinum. Mar 24, · 9. Lewis LN () In: Clarson SJ, Fitzgerald JJ, Owen MJ, Smith SD (Eds) Silicones and silicone-modified materials.
Oxford University Press and the American Chemical Society, Washington, DC, USA, pp 11–19Cited by: Get this from a library! Comprehensive handbook on hydrosilylation.
[Bogdan Marciniec;] -- This handbook provides an up-to-date account of hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are.
Comprehensive Handbook on Hydrosilylation. Book • Edited by: BOGDAN MARCINIEC. This handbook provides an up-to-date account of hydrosilylation reactions and the directions in which synthetic and mechanistic studies as well as practical applications of these processes are proceeding.
The book consists of two parts: the first is. Dec 13, · This first handbook to focus solely on the application of N-heterocyclic carbenes in synthesis covers metathesis, organocatalysis, oxidation and asymmetric reactions, along with experimental procedures.
Written by leading international experts this is a valuable and practical source for every organic chemist.